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The ratio of the masses percentages of 'C' and , 'H' and 'C' and, 'O' of a saturated acyclic organic compound 'X' are 4:1  and 3:4  respectively . Then , the moles of oxygen gas required  for complete combustion of two moles of organic compound 'X'  is_____________
 

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We have

Mass ratio of C:H = 4:1

Mass ratio of C:O = 3:4

Thus, mass ratio of C:H:O = 12:3:16

Mass ratio of C:H:O = 1:3:1

Thus, empirical formula = CH3O

Now, since (CH3O)n is saturated acyclic. Hence only possible value of n is 2.

Thus, the compound is C2H6O2.

Now, the reaction occurs as follows:

\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O_{2}}+\: \frac{5}{2}\mathrm{O}_{2} \rightarrow 2 \mathrm{CO}_{2}+3 \mathrm{H}_{2} \mathrm{O}

Thus, 5 moles of O2 are required for combustion of 2 moles of the organic compound.

 

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Kuldeep Maurya

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