The solubility of carbonates decreases down the magnesium group due to:
Increase in hydration energies of cation
Decrease in lattice energies of solids
Both a and b
Decrease in hydration energies of cation
As we learn
Solubility of carbonates of alkaline metals -
Decreases down the group. The insoluble metal carbonates dissolves in the presence of
-
The solubility of an ionic compound in water decreases with increase in lattice energy but increase with hydration energies
In alkaline earth metal group, the hydration energy of cation decreases from the top to bottom with increase in size of cation. However the lattice energy remains almost unchanged.
Therefore, option (4) is correct.