Browse by Stream
QnA
Home
QnA
Go To Your Study Dashboard

Get Answers to all your Questions

header-bg qa
  • Home
  • Medical
  • Barium ions, CN- and CO2+ form an ionic complex. If this complex is 75% ionised in aqueous solution with Vant Hoff factor (i) equal to four and paramagnetic moment i

Barium ions, CN- and CO2+ form an ionic complex. If this complex is 75% ionised in aqueous solution with Vant Hoff factor (i) equal to four and paramagnetic moment is found to be 1.73 BM(due to spin only) then the hybridisation state of CO(II) in the complex will be :

Option: 1

sp3d
 


Option: 2

d2sp3


Option: 3

sp3d2

 


Option: 4

dsp3


Answers (1)

 

Inner sphere complex -

Complexes in which (n-1)d orbitals are used in hyberdisation.

- wherein

For example: d^{2} sp^{3} hybrid \left [ Fe\left ( CN \right )_{6} \right ]

 

 

 

Strong Field Ligand -

These are the ligands which pair the electron in inner d-orbital and makes required d-orbitals empty/available. 

- wherein

For example: CO, CN etc

 

 

 

 

 

 

Ba_{(x-2)}[Co(CN)_{x}]_{2}\rightarrow (x-2)Ba^{2+}+2[Co(CN)_{x}]^{(x-2)}

1-\alpha                                (x-2)\alpha                                      2\alpha

i=1-\alpha +x\alpha -2\alpha +2\alpha

(x-1)\alpha =3\; x-1=\frac{3}{\alpha }

\alpha =0.75;     x=5

\therefore formula of complex is Ba_{3}[Co(CN)_{5}]_{2} and hybridisation is dsp3 as it is a inner orbital complex with strong field ligand.

 

Posted by

Ramraj Saini

View full answer

NEET 2024 Most scoring concepts

    Just Study 32% of the NEET syllabus and Score up to 100% marks

Similar Questions

Trending Articles/News

anam-khan

Who is AIR 1 in NEET 2025? Toppers and their marks in last 5 years
anam-khan

BAMS NEET cut-off trends for government Ayurveda colleges for General, OBC, SC, ST
anam-khan

NEET Result Date 2025 LIVE: NTA NEET UG results on June 14; cut-off trends for AIQ seats, top colleges

Latest Question