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Because of lanthanoid contraction, which of the following pairs of elements have nearly the same atomic radii? (Numbers in the parenthesis are atomic numbers).

Option: 1

Zr (40) and Hf (72)


Option: 2

Zr (40) and Ta (73)


Option: 3

Ti (22) and Zr (40)


Option: 4

Zr (40) and Nb (41)


Answers (1)

best_answer

Due to lanthanoid contraction, the atomic radii of Zr and Hf are nearly the same.

Hf has atomic number 72 and has an electronic configuration of [Xe]6s^24f^1^45d^2, due to the presence of electrons in poorly shielded f-orbitals. Effective nuclear charge experienced by outermost electrons increases and size of period 5 and 6 elements is nearly the same. 

The correct answer is option 1. 

Posted by

Ajit Kumar Dubey

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