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Match the compounds given in column I with the hybridisation and shape given in column II and mark the correct otpion.

  Column-I   Column-II
1. XeF_{6} (i) Distorted octahedral
2. XeO_{3} (ii) Square planar
3. XeOF_{4} (iii) Pyramidal
4. XeF_{4} (iv) Square pyramidal
  • Option 1)

    Code:

              1       2       3       4

             (i)      (iii)    (iv)     (ii)

  • Option 2)

    Code:

              1        2       3       4

             (i)       (ii)     (iv)   (iii)

  • Option 3)

    Code:

              1          2       3       4

             (iv)      (iii)     (i)      (ii)

  • Option 4)

    Code:

              1          2       3       4

             (iv)       (i)      (ii)     (iii)

 

Answers (1)

As we learnt in

 

Structure of Xenon tetrafluoride -

Square planar and hybridisation is Sp3d2

- wherein

 

 

Structure of Xenon hexafluoride -

Distorted octahedral and hybridisation is Sp3d3

- wherein

 

 

 

Oxide of Xenon -

XeF_2 + H_2O \rightarrow X_{e}+2HF+\frac{1}{2}O_{2}

2XeF_4 + 4H_2O \rightarrow X_{e}O_{3}+8HF+\frac{1}{2}O_{2}

 

- wherein

Due to high electronegativity of oxygen it form coumpound with Xe

 

 

Structure of Xenon XeOF4 (oxytetrafluoride) -

Sp3d2 hybridised and square pyramidal structure 

- wherein

 

Structure of Xenon XeOF4 (oxytetrafluoride) -

Sp3d2 hybridised and square pyramidal structure 

- wherein

 

  

 

 

 

Compound

Structure

1.

XeF_{6}

Distorted octahedral

2.

XeO_{3}

Pyramidal

3.

XeOF_{4}

square pyramidal

4.

XeF_{4}

Square planar

 

 

 

 

 

 


Option 1)

Code:

          1       2       3       4

         (i)      (iii)    (iv)     (ii)

this option is correct

Option 2)

Code:

          1        2       3       4

         (i)       (ii)     (iv)   (iii)

this option is incorrect

Option 3)

Code:

          1          2       3       4

         (iv)      (iii)     (i)      (ii)

this option is incorrect

Option 4)

Code:

          1          2       3       4

         (iv)       (i)      (ii)     (iii)

this option is incorrect

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