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Which of the following statements are incorrect?

A. All the transition metals except scandium form MO oxides which are ionic.
B. The highest oxidation number corresponding to the group number in transition metal oxides is attained in \mathrm{Sc}_2 \mathrm{O}_3 \,\, to\, \, \mathrm{Mn}_2 \mathrm{O}_7.
C. Basic character increases from \mathrm{V}_2 \mathrm{O}_3 \, \,\, to \, \, \mathrm{V}_2 \mathrm{O}_4 to \, \mathrm{V}_2 \mathrm{O}_5.
D.\mathrm{V}_2 \mathrm{O}_4 dissolves in acids to give \mathrm{VO}_4^{3-}salts.
E. CrO is basic but \mathrm{Cr}_2 \mathrm{O}_3 is amphoteric
Choose the correct answer from the options given below :

Option: 1

A and E only


Option: 2

B and D only
 


Option: 3

C and D only
 


Option: 4

B and C only


Answers (1)

best_answer

We know,

Acidic character increases with an increase in oxidation state because the tendency to gain electrons increases with the increase in oxidation state.

\text { Basic character decreases from } \mathrm{V}_2 \mathrm{O}_3 \text { to } \mathrm{V}_2 \mathrm{O}_4 \text { to } \mathrm{V}_2 \mathrm{O}_5 \text {. }

\mathrm{V}_2 \mathrm{O}_4 \text { dissolves in acids to give } \mathrm{VO}^{2+} \textup{ not }\mathrm{VO}_4^{3-} \text { salts. }

C and D are incorrect.

Posted by

avinash.dongre

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