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  • Which one of the following complexes is not expected to exhibit isomerism?Option: 1 <img alt="\left [ Ni(en)_{3} \right ]^{2+}" src="https://learn.ca

Which one of the following complexes is not expected to exhibit isomerism?

Option: 1

\left [ Ni(en)_{3} \right ]^{2+}


Option: 2

\left [ Ni(NH_{3})_{4}(H_{2}O)_{2} \right ]^{2+}


Option: 3

\left [ Pt(NH_{3})_{2}Cl_{2} \right ]


Option: 4

\left [ Ni(NH_{3})_{2}Cl_{2} \right ]


Answers (1)

best_answer

[Ni(NH_3)_{2}Cl_2] has tetrahedral geometry and thus, does not exhibit isomerism due to the presence of symmetry elements.

[Pt(NH_3)Cl_2]  is square planar in shape and shows geometrical isomerism. 

[Ni(en)_3]^2^+ shows optical isomerism. 

Hence, option number (4) is correct.

Posted by

Nehul

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