-
Engineering and Architecture
Exams
Colleges
Predictors
Resources
-
Computer Application and IT
Quick Links
Colleges
-
Pharmacy
Colleges
Resources
-
Hospitality and Tourism
Colleges
Resources
Diploma Colleges
-
Competition
Other Exams
Resources
-
School
Exams
Top Schools
Products & Resources
-
Study Abroad
Top Countries
Student Visas
-
Arts, Commerce & Sciences
Exams
Colleges
Upcoming Events
Resources
-
Management and Business Administration
Exams
Colleges & Courses
Predictors
-
Learn
Online Courses
Engineering Preparation
Medical Preparation
-
Online Courses and Certifications
Top Streams
Specializations
- Digital Marketing Certification Courses
- Cyber Security Certification Courses
- Artificial Intelligence Certification Courses
- Business Analytics Certification Courses
- Data Science Certification Courses
- Cloud Computing Certification Courses
- Machine Learning Certification Courses
- View All Certification Courses
Resources
-
Medicine and Allied Sciences
Colleges
Predictors
Resources
-
Law
Resources
Colleges
-
Animation and Design
Predictors & Articles
Colleges
Resources
-
Media, Mass Communication and Journalism
Exams
Colleges
Resources
-
Finance & Accounts
Top Courses & Careers
Colleges
Get Answers to all your Questions
Q. 11.15 Given below are observations on molar specific heats at room temperature of some common gases.
Gas Molar specific heat (Cv )
Hydrogen 4.87
Nitrogen 4.97
Oxygen 5.02
Nitric oxide 4.99
Carbon monoxide 5.01
Chlorine 6.17
The measured molar specific heats of these gases are markedly different from those for monatomic gases. Typically, molar specific heat of a monatomic gas is Explain this difference. What can you infer from the somewhat larger (than the rest) value for chlorine ?
Answers (1)
Monoatomic gases have only translational degree of freedom but diatomic gases have rotational degrees of freedom as well. The temperature increases with increase in the spontaneity of motion in all degrees. Therefore to increase the temperature of diatomic gases more energy is required than that required to increase the temperature of monoatomic gases by the same value owing to higher degrees of freedom in diatomic gases.
If we only consider rotational modes of freedom the molar specific heat of the diatomic gases would be given as
The number of degrees of freedom = 5 (3 translational and 2 rotational)
The values given in the table are more or less in accordance with the above calculated one. The larger deviation from the calculated value in the case of chlorine is because of the presence of vibrational motion as well.
Crack CUET with india's "Best Teachers"
- HD Video Lectures
- Unlimited Mock Tests
- Faculty Support
Similar Questions
- 0.3780 g of an organic chloro compound gave 0.5740 g of silver chloride in Carius estimation. Calculate the percentage of chlorine present in the compound.
- 1.0 mol of a monoatomic ideal gas is expanded from state (1) to state (2) as shown in figure. Calculate the work done for the expansion of gas from state (1) to state (2) at 298 K.
- At what temperature is the root mean square speed of an atom in an argon gas cylinder equal to the rms speed of a helium gas atom at – 20 °C ?
Trending Articles/News
Latest Question
- A sum of money under compound interest doubles itself in 4 years. In how many years will it become 16 times itself? Option: 1 1
- A certain loan amounts, under compound interest, compounded annually earns an interest of Rs.1980 in the second year and Rs.2178 in the third year. How much interest did it earn in the first year?<
