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In solid state $PCl_{5}$ is a _________.

(i) covalent solid

(ii) octahedral structure

(iii) ionic solid with $\left [ PCl_{6} \right ]^{+}$ octahedral and $\left [ PCl_{4} \right ]^{-}$ tetrahedra

(iv) ionic solid with $\left [ PCl_{4} \right ]^{+}$ tetrahedral and $\left [ PCl_{6} \right ]^{-}$ octahedral

Answers (1)

The answer is the option (iv).

Structure of $PCl_{5}$ in solid state

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