Extraction of silver
1) Silver occurs in both combined state as well as in the free state. The important ores of silver are Argentite (Ag2S) copper, silver glance, Horn silver, Ruby silver etc.
2) Silver is extracted from the ore-Argentite (Ag2S)
3) The ore is crushed, concentrated and then treated with sodium cyanide solution.
4) The reaction forms sodium Argento cyanide [Na[Ag(CN)2]].
Ag2S + 4 NaCN → 2 Na [Ag(CN)2] + 2 Ag.
5) This solution of sodium Argento cyanide combined with zinc dust forms tetra Ayano zincate and principle silver. This precipitated silver is called spongy silver.
Zn + 2 Na [Ag(CN)2] → Na2 [Zn(CN)4] + 2 Ag.
6) The spongy silver is fused with potassium nitrate to obtain pure silver. Then the silver obtained is purified by the electrolytic process.