Give reasons :
(i) shows the highest oxidation state of +7 with oxygen but with fluorine it shows the highest oxidation state of +4.
(ii) is soft whereas
is hard.
(iii) is a good reducing agent.
(i) shows the highest oxidation state of +7 with oxygen, but with fluorine it shows the highest oxidation state of +4, because of the ability of oxygen to form multiple bonds with transition metals
but fluorine cannot do so.
(ii) is soft but
is hard due to presence of strong metallic bonds in
and due to presence of 5 unpaired electrons in d-orbital, whereas
have weak metallic bonds in their lattices due to absence of unpaired d electrons.
(iii) is a good reducing agent because it has tendency to get oxidised to +3 state,and reach the most stable oxidation state.