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At 18C^{\circ} the conductance of H^+ and CH_3COO^- at infinite dilution are 315 AND 35 mho\: cm^2/eq. The quivalent conductivity of CH3COOH at infinte dilution in mho cm2 / eq is

  • Option 1)

    350

  • Option 2)

    280

  • Option 3)

    30

  • Option 4)

    315

 

Answers (1)

best_answer

As we learnt in 

Conductivity -

Inverse of resistivity is called conductivity. \kappa = \frac{1}{\rho } 

- wherein

SI unit of Conductivity = Sm^{-1}

 

 \Lambda_{\infty }\left ( H^{+} \right )=315\ mho\, \, cm^{2}\, \, eq^{-1}

\Lambda_{\infty }\left ( CH_{3}COO^{-} \right )=35 mho\, \, cm^{2}\, \, eq^{-1}

Now at \infty dilution , CH_{3}COOH completely dissociates to CH_{3}COO^{-} and H^{+}

CH_{3}COOH\rightleftharpoons CH_{3}COO^{-1}+H^{+}

\Lambda_{\infty }\left ( CH_{3}COOH \right )=\Lambda_{\infty }\left ( CH_{3}COO^{-} \right )+\Lambda_{\infty }\left ( H^{+} \right )

=315+35  mhocm^{2}\, \, eq^{-1}

=350\, \, mho\, \, cm^{2}\, \, eq^{-1}

\therefore Solution is 1

 


Option 1)

350

Correct

Option 2)

280

Incorrect

Option 3)

30

Incorrect

Option 4)

315

Incorrect

Posted by

Aadil

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