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  • Help me understand! Which of the following compounds exhibits linkage isomerism

Which of the following compounds exhibits linkage isomerism

  • Option 1)

    [Co(en)_{3}]Cl_{3}

  • Option 2)

    [Co(NH_{3})_{6}][Cr(CN_{6})]

  • Option 3)

    [Co(en)_{2}NO_{2}Cl]Br

  • Option 4)

    [Co(NH_{3})_{5}Cl]Br_{2}

 

Answers (1)

best_answer

As we have learned

Linkage Isomerism -

This isomerism arises in complexes containing ambidentate ligands.

- wherein

For example: \left [ Co\left ( NH_{3} \right )_{5}\left (NO_{2} \right ) \right ]Cl_{2}

Hence NO2  can connect by nitrogen and also by oxygen.

 

 [Co(en)_2NO_2Cl]Br;[Co(en_2)ONOCl]Br

 

 

 


Option 1)

[Co(en)_{3}]Cl_{3}

Option 2)

[Co(NH_{3})_{6}][Cr(CN_{6})]

Option 3)

[Co(en)_{2}NO_{2}Cl]Br

Option 4)

[Co(NH_{3})_{5}Cl]Br_{2}

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Aadil

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