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[Co(NH_{3})_{4}Cl_{2}]NO_{2}..and .. [Co(NH_{3})_{4}ClNO_{2}]Cl    are isomers

  • Option 1)

    Geometrical

  • Option 2)

    Optical

  • Option 3)

    Linkage

  • Option 4)

     Ionization

 

Answers (1)

As we have learned

Ionisation Isomerism -

This arises when a counter ion is exchanged with a ligand in square brackets.

 

- wherein

For example: \left [ Co\left ( NH_{3} \right )_{5} So_{4}\right ] Br, & \left [ Co\left ( NH_{3} \right )_{5} Br\right ] So_{4}

 

 

Both produce different ions in solution state-

[Co(NH_3)_4Cl_2]NO_2\rightleftharpoons [Co(NH_3)_4Cl_2]^{+}NO_2^{-}

[Co(NH_3)_4Cl\cdot NO_2]Cl\rightleftharpoons [Co(NH_3)_4Cl\cdot NO_2]^{+}+Cl^{-}

 

 

 


Option 1)

Geometrical

Option 2)

Optical

Option 3)

Linkage

Option 4)

 Ionization

Posted by

Vakul

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