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Of the following four aqueous solutions,total number of those solutions whose freezing point is lower than that of \mathrm{0.10\, M\, C_{2}H_{5}OH} is __________ (Integer answer)  \mathrm{(i)\: 0. 10\, M\ Ba_{3}\left ( PO_{4} \right )_{2}}
 \mathrm{(ii)\: 0.10\, M\ Na_{2}SO_{4}}
\mathrm{(iii)\: 0. 10\, M\ KCl}
\mathrm{(iv)\: 0.10\,M\ Li_{3}PO_{4}}
 

Answers (1)

best_answer

As we have learnt ,

\mathrm{\Delta T_{f}= i\, K_{f}\: \: m}
So, greater the value of 'i' , greater will be the depression in freezing point and lower will be the value of the freezing point.

\mathrm{(i)\; Ba_{3}\left ( PO_{4} \right )_{2},\;\;\;i= 5}
\mathrm{(ii)\;Na_{2}SO_{4},\;\;\;i= 3}
\mathrm{(iii)\;KCl,\;\;\;i= 2}
\mathrm{(iv)\;Li_{3}PO_{4},\;\;\;i= 4}

Thus, all given compounds have a greater value of van't Hoff factor than \mathrm{C_{2}H_{5}OH\left ( i= 1 \right )}

Hence, the correct answer is 4

Posted by

sudhir.kumar

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