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- Stuck here, help me understand: - Organic Compounds containing Halogens - JEE Main
- #Joint Entrance Examination Main
- #Chemistry
- #Organic Compounds containing Oxygen
- #Engineering
- #Organic Compounds containing Halogens
For which of the following parameters the structural isomers and
would be expected to have the same values? (Assume ideal behaviour)
- Option 1)
Heat of vaporisation
- Option 2)
Vapour pressure at the same temperature
- Option 3)
Boiling points
- Option 4)
Gaseous densities at the same temperature and pressure.
Answers (1)
As we learnt in
Physical properties of ether -
– Insoluble in water except dimethyl ether.
– Show dipole moment due to C - O polar bond.
– Boiling points of ether are lower than isomeric alcohol.Due to the presence of H-bonding in alcohol.
-
All the parameters will be different except the gaseous densities due to the presence of H-Bonding in alcohol which is absent in ether
Option 1)
Heat of vaporisation
This option is incorrect
Option 2)
Vapour pressure at the same temperature
This option is incorrect
Option 3)
Boiling points
This option is incorrect
Option 4)
Gaseous densities at the same temperature and pressure.
This option is correct
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