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Which complex shows limitation of CFT?

Option 1)
$[CoCl_6]^{3-}$

Option 2)
$[Ni(CO)_4]$

Option 3)
$[Fe(CN)_6]^{4-}$

Option 4)
$[Ag(CN)_2]^{-1}$

Answers (1)

As we learnt

Limitation of CFT -

Does not talk about covalent character
If metal and ligand are neutral, according to this theory complex should not form, but $\left [ Ni\left ( Co\right )_{4} \right ]$ exists

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Option 1)

$[CoCl_6]^{3-}$

Option 2)

$[Ni(CO)_4]$

Option 3)

$[Fe(CN)_6]^{4-}$

Option 4)

$[Ag(CN)_2]^{-1}$

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Vakul

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