The correct order of reactivity towards electrophilic substitution is
phenol>benzene>chlorobenzene>benzoic acid
benzoic acid>chlorobenzene>benzene>phenol
phenol>chlorobenzene>benzene>benzoic acid
benzoic acid>phenol>benzene>chlorobenzene
As we have learnt,
Groups showing (+M) effect donate the electron density to the benzene ring whereas the groups showing (-M) effect withdraw the electron density from benzene ring towards it.
Groups exerting +M effect activate the Benzene ring while those with -M effect deactivate the benzene ring
Thus order of reactivity is
phenol>benzene>chlorobenzene>Benzoic acid
Therefore, option (1) is correct.
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