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  • The number of geometrical isomers found in the metal complexes <img alt="\mathrm{\left[ PtCl _{2}\left( NH _{3}\right)_{2}\right],\left[ Ni ( CO )_{4}\right], \left[ Ru \left( H _{2} O \right)_{3} Cl _{3}\right] \text { and }\left[ CoCl _{2}\left( NH _

The number of geometrical isomers found in the metal complexes \mathrm{\left[ PtCl _{2}\left( NH _{3}\right)_{2}\right],\left[ Ni ( CO )_{4}\right], \left[ Ru \left( H _{2} O \right)_{3} Cl _{3}\right] \text { and }\left[ CoCl _{2}\left( NH _{3}\right)_{4}\right]^{+}} respectively, are :
Option: 1 1,1,1,1
Option: 2 1,1,1,1
Option: 3 1,1,1,1
Option: 4 1,1,1,1
Option: 5 2,1,2,2
Option: 6 2,1,2,2
Option: 7 2,1,2,2
Option: 8 2,1,2,2
Option: 9 2,0,2,2
Option: 10 2,0,2,2
Option: 11 2,0,2,2
Option: 12 2,0,2,2
Option: 13 2,1,2,1
Option: 14 2,1,2,1
Option: 15 2,1,2,1
Option: 16 2,1,2,1

Answers (1)

best_answer

The complexes along with their geometrical isomers are given below:

(a) \left [ \text { Pt} \left(\mathrm{NH}_{3}\right)_{2} \mathrm{Cl}_{2} \right ] : Square planar \text{Ma}_{2}\text{b}_{2}

(b) \text{Ni}(\text{CO})_{4} : tetrahedral complex.

Does not show Geometrical isomerism.

(c) \left[\mathrm{Ru}\left(\mathrm{H}_{2} \mathrm{O}\right)_{3} \mathrm{Cl}_{3}\right] : Octahedral \text {Ma}_{3}\text{b}_{3}

(d) \left[\mathrm{Co} \mathrm{Cl}_{2}\left(\mathrm{NH}_{3}\right) _{4}\right]^{+} : Octahedral \text{Ma}_{4}\text{b}_{2}

Hence, the correct answer is option (3)

Posted by

sudhir.kumar

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