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The wavelength of the first line of Lyman series for hydrogen atom is equal to that of the second line of Balmer series for a hydrogen like ion. The atomic number Z of hydrogen like ion is:

Option: 1

4


Option: 2

1


Option: 3

2


Option: 4

3


Answers (1)

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Lyman series of H-atom, we can write \frac{\mathrm{hc}}{\lambda}=\operatorname{Rhc}\left(\frac{1}{1^2}-\frac{1}{2^2}\right)

Where, symbols have their usual meaning and for second line of Balmer series of H-like ion

\frac{\mathrm{hc}}{\lambda}=\mathrm{Z}^2 \operatorname{Rhc}\left(\frac{1}{2^2}-\frac{1}{4^2}\right)

\text { Therefore, }\left(\frac{1}{1^2}-\frac{1}{2^2}\right)=Z^2\left(\frac{1}{4}-\frac{1}{16}\right)

\left(1-\frac{1}{4}\right)=Z^2\left(\frac{1}{4}-\frac{1}{16}\right) \Rightarrow Z=2.19=2

 

 

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vinayak

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