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Assertion: The volume strength of a solution of hydrogen peroxide decreases with an increase in the hardness of the water.

Reason: The hardness of water is caused by the presence of ions of calcium and magnesium. These ions react with hydrogen peroxide and reduce its volume strength.

Option: 1

Both assertion & reason are correct


Option: 2

Both assertion & reason are wrong


Option: 3

assertion is wrong & reason is correct


Option: 4

assertion is correct & reason is wrong


Answers (1)

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Hydrogen peroxide H_2O_2 is a powerful oxidizing agent and is used in various industries for bleaching, disinfection, and sterilization. The volume strength of H_2O_2  is defined as the amount of oxygen that can be released from a given volume of H_2O_2  solution. It is usually expressed in terms of the percentage of present in the solution. 

The hardness of water is caused by the presence of ions of calcium and magnesium. These ions react with H_2O_2 and reduce their volume strength. The reaction is given as follows:

Ca_2^++H_2O_2\rightarrow CaO_2+2H^+\: \: \: \: \: \:.... (1)\\

Mg_2^++H_2O_2\rightarrow MgO_2+2H^+\: \: \: \: \: \:.... (2)

Equations (1) and (2) show that the ions of calcium and magnesium react with H_2O_2 to form calcium peroxide CaO_2  and magnesium peroxide MgO_2 respectively. This reaction reduces the amount of H_2O_2 available for oxidation, thereby reducing its volume strength.

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Sumit Saini

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