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Which of the following is correct with respect to — I effect of the substituents ? (R = alkyl)

  • Option 1)

     — NH2 > — OR >  — F

  • Option 2)

     — NR2 < — OR < — F

  • Option 3)

    — NH2 < — OR < — F

  • Option 4)

     — NR2 > — OR > — F
     

     

 

Answers (1)

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As we learnt that

-I - effect (Negative inductive effect) -

Those atoms or group of atoms having more tendency to displace \sigma e - towards itself as compared to Hydrogen atom is called Negative Inductive effect

- wherein

 

 

Based on electronegativity

-I effect \Rightarrow — NH2 < — OR < — F

                                                   or

                                — NR2 < — OR < — F


Option 1)

 — NH2 > — OR >  — F

This is incorrect.

Option 2)

 — NR2 < — OR < — F

This is correct.

Option 3)

— NH2 < — OR < — F

This is incorrect.

Option 4)

 — NR2 > — OR > — F
 

 

This is incorrect.

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prateek

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