Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their
more extensive association of carboxylic acid via van der Waals force of attraction
formation of carboxylate ion
formation of intramolecular H-bonding
formation of intermolecular H-bonding
As we learnt that
Carboxylic acids -
Organic acid containing one or more carboxyl (-COOH) groups as a functional group.
- wherein
This is due to more extensive association through intermolecular H-bond
Option 1)
more extensive association of carboxylic acid via van der Waals force of attraction
This is incorrect.
Option 2)
formation of carboxylate ion
This is incorrect.
Option 3)
formation of intramolecular H-bonding
This is incorrect.
Option 4)
formation of intermolecular H-bonding
This is correct.