Consider the molecules CH4, NH3 and H2O. Which of the given statements is false?
The H - C - H bond angle in CH4, the H - N - H bond angle in NH3, and the H - O - H bond angle in H2O are all greater than 90o.
The H - O - H bond angle in H2O is larger than the H - C - H bond angle in CH4.
The H - O - H bond angle in H2O is smaller than the H - N - H bond angle in NH3.
The H - C - H bond angle in CH4 is larger than the H - N - H bond angle in NH3.
As we learnt in
VSEPR Theory -
1. The shape of the molecule is determined by repulsions between all of the electron pair present in valence shell.
2. Order of repulsion
3 Repulsion among the bond pair is directly proportional to the bond order and electronegativity difference between the central atom and the other atom.
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From the above fugure it is clear that H—O—H bond angle in is smaller than H—C—H bond angles in .
Option 1)
The H - C - H bond angle in CH4, the H - N - H bond angle in NH3, and the H - O - H bond angle in H2O are all greater than 90o.
This option is incorrect
Option 2)
The H - O - H bond angle in H2O is larger than the H - C - H bond angle in CH4.
This option is correct
Option 3)
The H - O - H bond angle in H2O is smaller than the H - N - H bond angle in NH3.
This option is incorrect
Option 4)
The H - C - H bond angle in CH4 is larger than the H - N - H bond angle in NH3.
This option is incorrect