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Match the interhalogen compounds of column-I with the geometry in column II and assign the correct code.

  Column-I   Column-II
1. XX' (i) T-shape
2. XX'_{3} (ii) Pentagonal bipyramidal
3. XX'_{5} (iii) Linear
4. XX'_{7} (iv) Square-pyramidal
    (v) Tetrahedral
  • Option 1)

    Code:

               1       2      3      4

             (iii)     (i)     (iv)   (ii)

  • Option 2)

    Code:

               1       2      3      4

              (v)     (iv)   (iii)   (ii)

  • Option 3)

    Code:

               1       2      3      4

              (iv)    (iii)    (ii)    (i)

  • Option 4)

    Code:

               1       2      3      4

              (iii)    (iv)   (i)     (ii)

 

Answers (1)

As we learnt in

Chlorine Monofluoride -

No hybridisation, polar 

- wherein

ClF is linear in shape 

 

 

Chlorine Trifluoride and iodine Trifluoride -

Sp3d hybridised and T-shaped 

- wherein

P-block element

 

 

Iodine Pentafluoride ......Bromine pentafluoride -

Sp3d2 hybridised and square pyramidal 

- wherein

 

 

Iodine heptafluoride -

Sp3d3 hybridised and pentagonal bipyramidal 

- wherein

 

 

 

 
Column-I
Column-II
1.
XX'
linear
2.
XX'_{3}
T-shaped
3.
XX'_{5}
Square pyramidal
4.
XX'_{7}
Pentagonal bipyramidal

 

 

 


Option 1)

Code:

           1       2      3      4

         (iii)     (i)     (iv)   (ii)

This option is correct

Option 2)

Code:

           1       2      3      4

          (v)     (iv)   (iii)   (ii)

This option is incorrect

Option 3)

Code:

           1       2      3      4

          (iv)    (iii)    (ii)    (i)

This option is incorrect

Option 4)

Code:

           1       2      3      4

          (iii)    (iv)   (i)     (ii)

This option is incorrect

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Vakul

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