The azeotropic mixture of acetone and methanol boils at . When this mixture is distilled, what can be obtained?
Pure acetone
Pure methanol
A solution with higher concentration of acetone
A solution with higher concentration of methanol
When an azeotropic mixture of acetone and methanol is distilled, it is not possible to obtain pure acetone or pure methanol through simple distillation. However, it is possible to obtain a solution that has a higher concentration of acetone or methanol than the original mixture.
This is because an azeotropic mixture has a constant boiling point and a constant composition in both the liquid and vapour phases. Therefore, when the mixture is distilled, the vapour that is produced has the same composition as the liquid being distilled. As a result, when the vapour is condensed, it forms a liquid that has the same composition as the original mixture.
However, by using a different distillation technique such as azeotropic distillation or extractive distillation, it is possible to break the azeotrope and obtain a solution with a higher concentration of acetone or methanol. Therefore, option C is the correct answer.