The deep blue colour of solution of sodium in ammonia is due to :
Sodium ion
Ammoniated sodium ion
Ammoniated electron
Sodium amide
As we have learnt ,
Color of alkali metal -ammonia solution -
Blue colour is due to excitation of free ammoniated electrons to higher energy levels absorbing energy in the visible region
In concentrated solution, blue colour changes to metallic copper or bronze due to metal ion cluster formation
Therefore, option(3) is correct.