The solubility order for alkali metal fluoride in water is :
LiF<RbF<KF<NaF
RbF<KF<NaF<LiF
LiF>NaF>KF>RbF
LiF<NaF<KF<RbF
LiI > NaI > KI > RbI > Cal (solubility)
Since r- > r+ ? the sum will not change too much as r+? increases. As a result, the lattice energy will not change significantly as r+? increases. Thus decreases in lattice energy are not as fast as decreases in hydration energy. Thus, more decreases in hydration energy result in decrease insolubility. Thus, solubility decreases as
LiI > NaI > KI > RbI > Cal
With a small anion as (F-) the lattice energy decreases more rapidly along with a series of salts with increasing cation size and thus solubility increases.
LiF < NaF < KF < RbF < CsF