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Which among the following is correct for all the alkali metals?

Option: 1

They readily react with halogens to form ionic halides, \mathrm{M^{+}X^{-}}


Option: 2

They react with water to form hydroxide and hydrogen

 


Option: 3

Their chlorides are deliquescent and crystallise as hydrates

 


Option: 4

Their nitrates decompose into nitrites and oxygen on heating


Answers (1)

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Halides of Li are covalent in nature due to its small size and high polarizing power.

All alkali metal will react with water to form hydroxides and liberate hydrogen.

2 \mathrm{M}+2 \mathrm{H}_2 \mathrm{O} \rightarrow 2 \mathrm{M}^{+}+2 \mathrm{OH}^{-}+\mathrm{H}_2 \text {, where } \mathrm{M}=\text { an alkali metal }

Among the chlorides of alkali metals, only LiCl is deliquescent (tend to absorb moisture) and crystallises as a hydrate \mathrm{LiCl} \cdot 2 \mathrm{H}_2 \mathrm{O}.

Nitrates of all alkali metals decompose into oxides on heating.

4 \mathrm{MNO}_3(\mathrm{~s}) \longrightarrow 2 \mathrm{M}_2 \mathrm{O}(\mathrm{s})+4 \mathrm{NO}_2(\mathrm{~g})+\mathrm{O}_2(\mathrm{~g}) \text {, where } \mathrm{M}=\text { an alkali metal }

Posted by

Gautam harsolia

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