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Which of the following purification technique is used for the separation of a mixture containing o-nitrophenol and p-nitrophenol?

Option: 1

Distillation


Option: 2

Steam distillation


Option: 3

Sublimation


Option: 4

Fractional Distillation


Answers (1)

best_answer

As we have learnt,

Steam Distillation 

This method is used to separate substances which are steam volatile and are immiscible with water.

e.g. Ortho-nitrophenol and Para-nitrophenol

Ortho nitrophenol is steam volatile because it has weaker intermolecular forces of attraction due to intramolecular H bonding.

Para nitrophenol is less steam volatile due to stronger intermolecular forces of attraction existing due to intermolecular H bonding.

Hence, the correct answer is Option (2)

Posted by

Shailly goel

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