Which of the following purification technique is used for the separation of a mixture containing o-nitrophenol and p-nitrophenol?
Distillation
Steam distillation
Sublimation
Fractional Distillation
As we have learnt,
Steam Distillation
This method is used to separate substances which are steam volatile and are immiscible with water.
e.g. Ortho-nitrophenol and Para-nitrophenol
Ortho nitrophenol is steam volatile because it has weaker intermolecular forces of attraction due to intramolecular H bonding.
Para nitrophenol is less steam volatile due to stronger intermolecular forces of attraction existing due to intermolecular H bonding.
Hence, the correct answer is Option (2)