Get Answers to all your Questions

header-bg qa

Which of the following statement is in favour regarding non-ideal solutions showing negative deviation from Raoult's law?

Option: 1

The vapour pressure of the solution is higher than predicted by Raoult's law.


Option: 2

The intermolecular forces between like molecules are stronger than those between unlike molecules.


Option: 3

The observed boiling point of the solution is higher than predicted by Raoult's law.

 


Option: 4

The observed freezing point of the solution is lower than predicted by Raoult's law.


Answers (1)

best_answer

In a non-ideal solution showing negative deviation from Raoult's law, the intermolecular forces between unlike molecules are stronger than those between like molecules. This causes the molecules to stick together more tightly, making it harder for them to escape into the vapour phase. As a result, the vapour pressure of the solution is lower than predicted by Raoult's law.

According to the boiling point elevation equation, the observed boiling point of a solution is higher than that of the pure solvent due to the presence of solute molecules in the solution. However, in the case of negative deviation from Raoult's law, the observed boiling point is even higher than predicted by Raoult's law. This happens because the intermolecular forces between unlike molecules are stronger, making it harder for the solvent molecules to escape into the vapour phase and causing the boiling point to increase.

Therefore, option C, "The observed boiling point of the solution is higher than predicted by Raoult's law" is the correct statement regarding non-ideal solutions showing negative deviation from Raoult's law.

 

Posted by

chirag

View full answer

NEET 2024 Most scoring concepts

    Just Study 32% of the NEET syllabus and Score up to 100% marks