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Aryl chlorides and bromides can be easily prepared by electrophilic substitution of arenas with chlorine and bromine respectively in the presence of Lewis acid catalysts. But why does the preparation of aryl iodides require the presence of an oxidizing agent?

 

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Iodination reactions are reversible in nature as because HI is formed in the process. To keep the reaction in forward direction, we need to remove the HI by oxidation process by adding some oxidizing agents like HIO_{4}.

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