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4.1 From the rate expression for the following reactions determine their order of reaction and the dimensions of the rate constants.

(ii) $H_{2}O_{2}(aq)+3I^{-}(aq)+2H^{+}\rightarrow 2H_{2}O(I)+I_{3}^{-}$ $Rate=k\left [ H_{2}O_{2}\right ]\left [ I^{-} \right ]$

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Given rate = $k[H_{2}O_{2}][I^{-}]$

therefore the order of the reaction is 2

Dimension of k = $rate/[H_{2}O_{2}][I^{-}]$

$\\=mol\ L^{-1}\ s^{-1}/(mol\ L^{-1})(mol\ L^{-1})\\ =L\ mol^{-1}\ s^{-1}$

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manish

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