9.4   Give evidence that following is ionisation isomer.

             (i) [Co(NH_{3})_{5}Cl]SO_{4}

 

Answers (1)

The ionisation isomers dissolve in water to yield different ions and thus react differently to various reagents:

[Co(NH3)5Br]SO4 + Ba2+ → BaSO4 (s)

[Co(NH3)5SO4]Br + Ba2+ → No reaction

[Co(NH3)5Br]SO4 + Ag+ → No reaction

[Co(NH3)5SO4]Br + Ag+ → AgBr (s)

 

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