9.3  Indicate the types of isomerism exhibited by the following complexes and draw the structures for these isomers:

           (iii) [Co(NH_{3})_{5}(NO_{2})](NO_{3})_{2}

 

 

Answers (1)

[Co(NH_{3})_{5}(NO_{2})](NO_{3})_{2}

There are 10 possible isomers.There are geometrical, ionisation and linkage isomers possible.

A pair of optical isomer

it also shows ionization isomerism

[Co(NH_{3})_{5}(NO_{2})](NO_{3})_{2}   AND [Co(NH_{3})_{5}(NO_{3})](NO_{3})(NO_2)

It can also show linkage isomerism

[Co(NH_{3})_{5}(NO_{2})](NO_{3})_2  AND  [Co(NH_{3})_{5}(ONO)](NO_{3})_2

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