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What do you understand by the term 'non-stoichiometric hydrides'? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer

9.11  What do you understand by the term “non-stoichiometric hydrides”? Do you expect this type of the hydrides to be formed by alkali metals? Justify your answer

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R Rakesh

Answer-

Non-stoichiometric hydrides are hydrogen deficient compounds. they are formed by d & f block elements. Such hydrides do not follow the law of constant composition. 

Examples- LaH_{2.87},YbH_{2.55},ZrH_{1.3-1.75} etc.

Alkali metals do not form these types of hydrides. Alkali metals form stoichiometric hydrides. These hydrides are ionic in nature.

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