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(a) Give one chemical test as an evidence to show that

$\left [ CO(NH_{3})_{5}Cl \right ]SO_{4}$ and $\left [ CO(NH_{3})_{5}(SO)_{4} \right ]Cl$ are ionization isomers.

(b) $\left [ NiCl_{4} \right ]^{2-}$ is paramagnetic while $\left [ Ni(CO)_{4} \right ]$ is diamagnetic though both are tetrahedral. Why ? (Atomic no. of $Ni=28$ )

(c) Write the electronic configuration of $Fe(III)$ on the basis of crystal field theory when it forms an octahedral complex in the presence of

(i) strong field ligand, and

(ii) weak field ligand. (Atomic no. of $Fe=26$ )

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