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What type of azeotropic mixture will be formed by a solution of acetone and chloroform ? Justify on the basis of strength of intermolecular interactions that develop in the solution.

 

 

 

 
 
 
 
 

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Mixture of acetone and chloroform form maximum boililng azeotrophes.in pure state acetone has dipole. dipole attractions whereas CHCl_{3} has rander waals forces, when two are mixed they form H-bonds with each other, this increases the forces in solution and and hence shows negative derivations from Roult's law.

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Sumit Saini

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