74.5 g of a metallic chloride contain 35.5 g of chlorine. The equivalent weight of the metal is
19.5
35.5
39
78
74.5 g of a metallic chloride contain 35.5 g of chlorine.
Therefore, weight of other element present in the chloride is
= Weight of Metal Chloride - Weight of Chloride
= 74.5 - 35.5 = 39 g
Thus, 39 g of the metal combines with 35.5 g of Chlorine
Mole of Chloride present = weight/molar mass = 35.5/35.5 = 1 mole
So, one mole of Cl is present and we know the charge on Cl is (-1).
So, MCl configuration will be there where M-metal.
MCl = M++ Cl-
So, one mole of Metal will be present and the charge would be (+1) on metal.
Molecular weight = mass of 1 mol metal = 39 g
Equivalent Weight = Molecular weight/ Valency.
Equivalent Weight = 39/1 =39
hence, the equivalent weight of the metal is 39.
Therefore, the correct option is (3)
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