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Calculate the change in entropy (S) when 2 moles of an ideal gas expand isothermally and reversibly from a volume of 10 L to a volume of 20 L at a temperature of 300 K.

Option: 1

 -12 JK
 


Option: 2

-11.52 J-K
 


Option: 3

 -11.52 J/K
 


Option: 4

 -11.52 kJ/K


Answers (1)

best_answer

The change in entropy (?S) for an isothermal and reversible expansion of an ideal gas can be calculated using the equation:

\mathrm{\Delta S=n R \ln \left(\frac{V_f}{V_i}\right)}

where n is the number of moles of the gas, R is the ideal gas constant (8.314 J/(mol·K)), \mathrm{V_f} is the final volume, and \mathrm{V_i} is the initial volume.

Given:

\mathrm{\begin{aligned} n & =2 \text { moles } \\ R & =8.314 \mathrm{~J} /(\mathrm{mol} \cdot \mathrm{K}) \\ V_f & =20 \mathrm{~L} \\ V_i & =10 \mathrm{~L} \end{aligned}}

Substituting the values and calculating:

\mathrm{\Delta S=2 \times 8.314 \mathrm{~J} /(\mathrm{mol} \cdot \mathrm{K}) \times \ln \left(\frac{20 \mathrm{~L}}{10 \mathrm{~L}}\right)}

Therefore, the change in entropy (?S) is approximately ?S = −11.52 J/K.
So, option c is correct

 

 

 

Posted by

Ritika Harsh

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