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In an experiment on the photo-electric effect, singly ionized helium is excited electronically to different energy levels. The light emitted by ionised helium is incident on a photo-electric plate in a photocell. When helium is excited to fourth energy level, then the observed “stopping potential” of the photocell is found to be five times the stopping potential measured when the photoelectrons are produced by using light emitted by hydrogen atom, excited to the third energy level. The work function of then material of the photo-electric plate is:

Option: 1

3.96 \mathrm{eV}


Option: 2

2.36 \mathrm{eV}


Option: 3

6.8 \mathrm{eV}


Option: 4

2.55 \mathrm{eV}


Answers (1)

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Energy of the photon with the highest frequency in the emission spectrum is
For helium (excited to the 4^{\text {th }} level) : \mathrm{f}_1=(2)^2 \mathrm{R} \mathrm{c}\left[\frac{1}{1^2}-\frac{1}{4^2}\right]
For hydrogen (excited to the 3^{\text {rd }} level) : \mathrm{f}_2=\mathrm{Rc}\left[\frac{1}{1^2}-\frac{1}{3^2}\right]
Using Einstein's equation of the photo-electric effect, we obtain,
\mathrm{hf}_1-\mathrm{W}=\mathrm{eV}_1 \\ \mathrm{hf}_2-\mathrm{W}=\mathrm{eV}_2 \\
where \mathrm{V}_1=5 \mathrm{~V}_2 (given)
Using (3), (4) and (5) we obtain,
\frac{\mathrm{hf}_1-\mathrm{W}}{\mathrm{e}}=5\left(\frac{\mathrm{hf}_2-\mathrm{W}}{\mathrm{e}}\right)
\Rightarrow 4 \mathrm{~W}=\mathrm{h}\left(5 \mathrm{f}_2-\mathrm{f}_1\right)
\Rightarrow \mathrm{W}=\frac{\mathrm{h}}{4}\left[5 \mathrm{f}_2-\mathrm{f}_1\right]
Putting the values of f_1  and f_2  from (1) and (2) in (6) we obtain,

\mathrm{W}=\frac{\mathrm{h}}{4}\left[\left(1-\frac{1}{9}\right) 5 \mathrm{Rc}-4\left(1-\frac{1}{16}\right) \mathrm{Rc}\right]=\frac{\mathrm{h}}{4} \mathrm{Rc}\left[\frac{8 \times 5}{9}-\frac{15}{4}\right]=0.694 \mathrm{Rhc}
Putting Rhc =13.6 \mathrm{eV} we obtain

\mathrm{W}=2.36 \mathrm{eV}

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Divya Prakash Singh

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