Given reaction:

Theoretically calculation:-
So, from 78 g of benzene on nitration gives 123 g of nitrobenzene.
1 g of Benzene on nitration gives 123/78 g of nitrobenzene.
3.9 g of benzene on nitration gives 3.9 x(123/78) g of nitrobenzene.
3.9 g of benzene on nitration gives 6.15 g of nitrobenzene.
But the actual amount of nitrobenzene formed is 4.92 g.
Ans = 80
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