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  • The reaction white phosphorus on boiling with alkali in inert atmosphere resulted inthe formation of product 'A'. The reaction of 1 mol of 'A' with excess of in aqueous medium gives _

The reaction white phosphorus on boiling with alkali in inert atmosphere resulted inthe formation of product 'A'. The reaction of 1 mol of 'A' with excess of AgNO_{3} in aqueous medium gives ________mol (s) of Ag. (Round off to the Nearest Integer).
Option: 1 4
Option: 2 -
Option: 3 -
Option: 4 -

Answers (1)

best_answer

The reaction of white phosphorus on boiling with alkali in the inert atmosphere resulted in the formation of the product 'A'.

\mathrm{P}_{4}+3 \mathrm{OH}^{-}+3 \mathrm{H}_{2} \mathrm{O} \rightarrow \mathrm{PH}_{3}+\underset{\text { (A) }}{3 \mathrm{H}_{2} \mathrm{PO}_{2}^{-}}

The reaction 1 mol of 'A' with an excess of AgNO3 in an aqueous medium gives 4 moles of Ag.

\underset{1 \text { mole }}{\mathrm{H}_{2} \mathrm{PO}_{2}^{-}}+\underset{\text { excess }}{4 \mathrm{Ag}^{+}}+2 \mathrm{H}_{2} \mathrm{O} \rightarrow \underset{4 \text { mole }}{4 \mathrm{Ag}\ +\ } \mathrm{H}_{3} \mathrm{PO}_{4}+3 \mathrm{H}^{+}

Ans = 4

Posted by

Kuldeep Maurya

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