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What is the amount (in moles) of peroxydisulfuric acid produced during electrolysis of sulfuric acid with high charge density if at 273 \mathrm{~K} and 1 \mathrm{~atm},\ 44.8 \mathrm{~L}\ \ \mathrm{L^{ \textrm {H } _ { 2 }}} and 16.8 \mathrm{~L}\ \mathrm{O}_{2} produced at the electrodes.

Option: 1

0.5


Option: 2

0.75


Option: 3

0.25


Option: 4

1.0


Answers (1)

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\mathrm{\begin{aligned} & \mathrm{Eq} \text { of } \mathrm{H}_2=\mathrm{Eq}_{\text {}} \text { of } \mathrm{O}_2+\mathrm{Eq} \text { of } \mathrm{H}_2 \mathrm{~S}_2 \mathrm{O}_8 \\ & 2 \times \frac{44.8}{22.4}=\frac{4 \times 16.8}{22.4}+2 \times n \\ & 4=3+2 n \\ & n=0.5 \\ & \end{aligned}}

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Rishi

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