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When \mathrm{FeCl}_{3} solution is added to \mathrm{NaOH} a negatively charged sol is obtained. It is due to the:

Option: 1

 Presence of basic group


Option: 2

Preferential adsorption of \mathrm{OH}^{-}ions


Option: 3

Self dissociation


Option: 4

Electron capture by sol particles


Answers (1)

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When \mathrm{FeCl}_{3} sol is treated with hot water, it forms \mathrm{Fe}(\mathrm{OH})_{3} forming \mathrm{Fe}^{3+}ions(in excess amount) and these positive ions are adsorbed preferentially. Further, when \mathrm{NaOH} is mixed, again there is formation of \mathrm{Fe}(\mathrm{OH})_{3} but now \mathrm{OH}^{-}
ions are in excess. Therefore, they will get preferentially adsorb and form negatively charged colloid.    

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Devendra Khairwa

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