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IMG_20190227_132117.jpg 153. Which of the following is correct with respect to — I effect of the substituents? (R = alkyl) (1) - NH2 < -OR < -F (2) - NR2 < - OR < -F (3) - NR2 > - OR > -F (4) -NH2 > -OR > -F

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@anchal

-I - effect (Negative inductive effect) -

Those atoms or group of atoms having more tendency to displace \sigma e - towards itself as compared to Hydrogen atom is called Negative Inductive effect

- wherein

 

 

Based on electronegativity

-I effect \Rightarrow — NH2 < — OR < — F

                                                   or

                                — NR2 < — OR < — F

-I effect H3C-NH2 3 C NH H3C 2 C
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Ankit

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