From the following pairs of ions which one is not an iso-electronic pair ?
The number of electrons present in the given ions-
O2- ⇒ 18
F- ⇒ 18
Na+ ⇒ 10
Mg2+ ⇒ 10
Mn2+ ⇒ 23
Fe3+ ⇒ 23
Fe2+ ⇒ 24
So, the pair of ions is not an iso-electronic pair.
Therefore, the correct option is (4).