The alkaline earth metal nitrate that does not crystalline with water molecule is -
A saturated aqueous solution of Hydration of an ion depends on its size. Smaller the size of an ion, higher will be its charge density and as a result it will remain more solvated (hydrated) through ion dipole interaction.
Size of group 2 metals ions increases on going down the group. So, their ability to form hydrated crystals follows the orders:-
Thus, is slightly or almost soluble in water.
Hence 3 is correct option