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Three moles of an ideal gas being initially at a temperature \mathrm{T}_0=273 \mathrm{~K} were isothermally expanded \mathrm{\eta=5.0} time its initial volume and then isochorically heated so that the pressure in the final state became equal to that in the initial state. The total amount of heat transferred to the gas during the process equals \mathrm{Q}=80 \mathrm{KJ}. Find the ratio \mathrm{\gamma=\mathrm{Cp} / \mathrm{Cv}} for this gas.
 

Option: 1

1.23


Option: 2

1.33


Option: 3

1.4


Option: 4

1.5


Answers (1)

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In isothermal process, the heat transferrd to the gas is given by

\mathrm{ \mathbf{Q}_{\mathbf{l}}=\mathbf{n R T} \mathbf{R} \ln \left(\mathbf{V}_2 / \mathbf{V}_{\mathbf{l}}\right)=\mathbf{n R T} \mathbf{T}_0 \ln \eta }          (1)

\mathrm{ {\left[\therefore \quad \eta=\left(\mathbf{V}_2 / \mathbf{V}_1\right)=\left(\mathrm{P}_1 / \mathbf{P}_2\right)\right. \text { ] }} }

\mathrm{ \text { In isochroric process, } \mathrm{Q}_2=\Delta \mathrm{U} \quad(\mathrm{W}=\mathbf{0}) }

\mathrm{ \therefore \quad \mathrm{Q}_2=\mathrm{nCv} \Delta \mathrm{T}=\mathbf{n}\{\mathrm{R} /(\gamma-\mathbf{1})\} \Delta \mathrm{T} }          (2)

\mathrm{ \text { Now } \frac{P_2}{P_1}=\frac{T_0}{T} \quad \text { or } \quad T=T_0\left(\frac{P_1}{P_2}\right)=\eta T_0 }

\mathrm{ \therefore \quad \Delta T=\eta T_0-T_0=(\eta-1) T_0 }           (3)

substituting the value of \mathrm{\Delta T} from equation (3) in equation (2), we get

\mathrm{ Q_2=n\left(\frac{R}{\gamma-1}\right)(\eta-1) T_0 }

\mathrm{ \therefore \quad Q=n R T_0 \ln \eta+n\left(\frac{R}{\gamma-1}\right)(\eta-1) T_0 }

\mathrm{ \text { or } \frac{Q}{\mathrm{nRT}_0}-\ln \eta=\left(\frac{\eta-1}{\gamma-1}\right) }

\mathrm{ \text { or } \quad \gamma-1=\frac{\eta-1}{\frac{Q}{\mathrm{nRT}}-\ln \eta} }

\mathrm{ \therefore \quad \gamma=1+\frac{\eta-1}{\frac{Q}{\mathrm{nRT_{0 }}}-\ln \eta} }

Substituting given values, we get

\mathrm{ \gamma=1+\frac{(5-1)}{\frac{80 \times 10^3}{3 \times 8.3 \times 273}-\ln 5} }

Solving we get \mathrm{ \gamma=1.4 }

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