Valve present over left auriculo-ventricular opening is
Semilunar valve
Tricuspid valve
Valve of Thebesian
Bicuspid valve
Mitral valve (bicuspid valve) - The atrioventricular opening between the left atrium and the left ventricle is guarded by mitral valve or bicuspid valve. It prevents backflow from the left ventricle into the left atrium. Hence, the correct answer is option d.